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4. 3. Decomposition of hexaphenylethane in constant-volume batch reactor; point-by-point evaluation. 96 spotting suspect data points. For instance, the coefficient value for the time interval from 174 to 209 seconds is out of line, making one suspect an error in one of the two times or concentrations used for calculating it. Apart from that value, the greatest deviations from the average are at the lowest and highest conversions. In general, these results are the least reliable and might be given less weight.

6. J. H. van't Hoff, Etudes de dynamique chimique, Muller, Amsterdam, 1884; see also any text on physical chemistry or chemical engineering. Denbigh (ref. 5. Hill (ref. 3. R. C. Tolman, Phys. , 23 (1924) 693. R. C. Tolman, The principles of statistical mechanics. Clarendon Press, Oxford, 1938 (reprint Dover, New York, 1979, ISBN 0486638960), p. 163. K. O. Denbigh, The thermodynamics of the steady state, Methuen, London, 1951, p. 31. Denbigh (ref. 02), p. 448. Hill (ref. 4. Chapter 3 Determination of Rates, Orders, and Rate Coefficients The first order of business in the study of a new reaction in the context of process research and development is to measure reaction rates, establish approximate reaction orders for empirical power-law rate equations, and obtain values of their apparent rate coefficients.

J. W. Moore and R. O. Pearson, Kinetics and mechanism. , 1981, ISBN 0471035580. Specific references 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. J. A. Christiansen, Reaktionskineticske studier, thesis. University of Copenhagen, 1921, p. 58. F. A. Lindemann, Trans. Faraday Soc, 17 (1922) 598. C. N. Hinshelwood, Proc. Roy. Soc, A 113 (1927) 230. H. Eyring, /. Chem. , 3 (1935) 107. W. F. K Wynne-Jones and H. Eyring, J. Chem. , 3 (1935) 492. S. Olasstone, K. J. Laidler, and H. Eyring, The theory of rate processes, McOrawHill, New York, 1941, Chapter VIII.

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A characteristic property of spherical caps by Ripoll J.

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